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Clopyralid

Basic information

  • Product Name:Clopyralid
  • CasNo.:1702-17-6
  • MF:C6H3Cl2NO2
  • MW:

Physical and Chemical Properties

  • Purity:96%
  • Boiling Point:
  • Packing:crystal
  • Throughput:
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Product Details

CasNo: 1702-17-6

MF: C6H3Cl2NO2

Appearance: crystal

Delivery Time: 15 days

Packing: 25kg/bag

Purity: 96%

1. Basic Information

  • English Common Name: Clopyralid
  • Other Names: Lontrel II, Stinger
  • Chemical Name: 3,6-Dichloropyridine-2-carboxylic acid
  • CAS Number: 1702-17-6
  • Molecular Formula: C₆H₃Cl₂NO₂
  • Molecular Weight: 192.0

2. Physicochemical Properties

  • Appearance: Pure product is a colorless crystal.
  • Melting Point: 151-152℃
  • Vapor Pressure: 1.33 mPa (at 24℃), 16 mPa (at 25℃)
  • Density: 1.57 g/cm³ (at 20℃)
  • Solubility (at 25℃):
    • In water: 7.85 g/L (distilled water), 118 g/L (pH 5), 143 g/L (pH 7), 157 g/L (pH 9)
    • In organic solvents: 121 g/L in acetonitrile, 6 g/L in n-hexane, 104 g/L in methanol
    • It can form water-soluble potassium salts with a solubility of >300 g/L.
  • Stability: Stable below its melting point, photostable, and stable in acidic media. The hydrolysis DT₅₀ (half-life) in sterile water at pH 5-8 (25℃) is >30 days.

3. Toxicity

It is a low-toxicity pesticide:

 

  • Acute oral LD₅₀ for rats: >4300-5000 mg/kg
  • It causes irritation to the eyes.

4. Mechanism of Action

Clopyralid is a systemic post-emergence herbicide. It can be absorbed by the roots, stems, and leaves of weeds, then translocated within the plant. It exerts its weed-control effect by inhibiting cell division and growth in weeds.

5. Efficacy

It controls annual broad-leaved weeds and deep-rooted perennial broad-leaved weeds in fields of oilseed rape, corn, lawns, etc. It has a specific effect on perennial weeds of the legume (Fabaceae) and aster (Asteraceae) families.

6. Formulations

Main formulations include:

 

  • 95% Clopyralid Technical Material (TC)
  • 75% Clopyralid Water-Dispersible Granules (WDG)
  • 75% Clopyralid Dispersible Powder (DF)
  • 30% Clopyralid Soluble Liquid (SL)

7. Suitable Crops & Application Methods

  • Spring Wheat Fields:
    Conduct foliar spraying when spring wheat is at the 3-5 leaf stage and annual broad-leaved weeds are at the 2-4 leaf stage. The application rate is 45-60 mL per mu (1 mu ≈ 0.0667 hectares), diluted in 30 kg of water per mu. It can be used a maximum of once per crop season.

8. Precautions

  • When applying the pesticide, avoid drift of the spray solution to sensitive crops such as soybeans, peanuts, and lettuce to prevent phytotoxicity.
  • Under the recommended dosage, the following crops can be safely planted in the subsequent stubble 60 days after application: wheat, barley, corn, oilseed rape (not applicable to brassica juncea), and cruciferous vegetables.
  • A 1-year interval is required if soybeans, peanuts, etc., are to be planted in the subsequent stubble.
  • An 18-month interval is required if cotton, sunflowers, watermelons, tomatoes, adzuki beans, mung beans, or sweet potatoes are to be planted in the subsequent stubble.