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Diethylamine

Basic information

  • Product Name:Diethylamine
  • CasNo.:109-89-7
  • MF:C4H11N
  • MW:

Physical and Chemical Properties

  • Purity:99%
  • Boiling Point:
  • Packing:liquid
  • Throughput:
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Product Details

CasNo: 109-89-7

MF: C4H11N

Appearance: liquid

Delivery Time: 15 days

Packing: 200kg/drum

Purity: 99%

1. Basic Information

  • Chinese Name: 二乙胺 (Diethylamine)
  • English Name: Diethylamine
  • CAS Number: 109-89-7
  • Molecular Formula: C₄H₁₁N
  • Molecular Weight: 73.14
  • Appearance: Colorless transparent liquid, free of mechanical impurities.

2. Physicochemical Properties

  • Melting Point: -50℃ (low freezing point, remains liquid in most indoor environments).
  • Boiling Point: 55℃ (high volatility; vapor easily accumulates at room temperature, requiring sealed storage).
  • Relative Density: 0.71 g/cm³ (at 20℃, lighter than water, so spilled liquid floats on water surfaces).
  • Flash Point: -23℃ (highly flammable; classified as a "flammable liquid"—vapors can ignite when in contact with open flames or static electricity).
  • Solubility: Miscible with water, alcohols (e.g., ethanol, methanol), and ethers; aqueous solutions exhibit strong alkalinity.
  • Corrosiveness: Strongly alkaline. Reacts with inorganic acids to form soluble salts; causes severe corrosion to skin, eyes, and most metals (e.g., iron, aluminum), requiring anti-corrosion packaging.
  • Volatility: Highly volatile; vapor density is 2.52 (heavier than air), so vapors tend to spread along the ground and accumulate in low-lying areas, increasing fire and toxicity risks.

3. Quality Indicators

Typical industrial-grade Diethylamine follows national and internal quality standards, with the following key specifications (taking premium grade products as an example):

 

Quality Indicator National Premium Grade Standard Internal Control Standard Description
Diethylamine Content ≥99.5% ≥99.7% Core active component; higher purity ensures stability in downstream reactions.
Ethylamine (Monoethylamine) Content ≤0.05% ≤0.05% Primary amine impurity; excessive levels may reduce the selectivity of pharmaceutical/pesticide synthesis.
Triethylamine Content ≤0.1% ≤0.1% Tertiary amine impurity; affects the yield of target products in fine chemical applications.
Ethanol Content ≤0.1% ≤0.1% Residual solvent from raw materials; high content may cause side reactions in organic synthesis.
Water Content ≤0.1% ≤0.1% Controls moisture to prevent hydrolysis of amine groups or corrosion of metal equipment.
Unknown Impurities Not specified ≤0.1% Strictly limits unidentifiable trace impurities for high-end application scenarios (e.g., pharmaceutical intermediates).
Color (APHA) ≤15 ≤15 Measures liquid clarity; lower values indicate fewer organic impurities (e.g., oxidized by-products).

4. Applications

  • Pharmaceutical Industry: Serves as a critical intermediate for synthesizing drugs such as local anesthetics (e.g., procaine), antihistamines, and sedatives. It also acts as a neutralizer in drug purification processes.
  • Pesticide Industry: Used to produce organophosphorus insecticides (e.g., parathion) and herbicides. Its alkalinity enhances the stability and efficacy of pesticide formulations.
  • Chemical Synthesis: Manufactures rubber vulcanization accelerators (improves rubber elasticity and durability), textile auxiliaries (e.g., softeners, antistatic agents), and metal preservatives (prevents corrosion of iron/steel parts).
  • Solvent Applications: Functions as a refining solvent for waxes and oils (removes impurities via acid-base reactions) and as an activator in emulsion polymerization of conjugated dienes (e.g., butadiene rubber synthesis).
  • Other Fields: Formulated into engine antifreeze (lowers the freezing point of coolant) and used as a polymerization inhibitor (prevents unwanted polymerization of vinyl monomers during storage).

5. Packaging, Transportation, and Storage

  • Packaging:
    • Industrial bulk packaging: Closed steel drums (inner wall coated with anti-corrosion resin to avoid metal-amine reactions), tank trucks, or rail tank cars (equipped with pressure relief valves to prevent vapor buildup).
    • Small-volume packaging: Customized sealed HDPE plastic bottles (for laboratory R&D or small-batch use) as agreed between suppliers and buyers, ensuring compliance with safety regulations.
  • Transportation:
    • Classified as a "dangerous good" (UN number: 1154). Avoid generating static electricity or sparks during loading/unloading (use grounded equipment).
    • Prohibit contact with skin—operators must wear chemical-resistant gloves and goggles. Do not transport with oxidizing agents, strong acids, or halogens (e.g., chlorine).
  • Storage:
    • Store in a cool, dry, well-ventilated warehouse (temperature ≤30℃) away from ignition sources (e.g., heaters, open flames) and direct sunlight.
    • Keep containers tightly sealed to prevent volatilization and moisture absorption. Separate from incompatible substances (e.g., nitric acid, hydrogen peroxide) to avoid violent reactions.

6. Safety Information

  • Hazards: Vapors are toxic and irritating—inhaling high concentrations can cause respiratory tract inflammation or dizziness; skin/eye contact may lead to chemical burns.
  • Protective Measures: Wear acid-base resistant gloves, splash-proof goggles, and a gas mask (equipped with amine-specific filters) during handling.
  • Emergency Handling: In case of a spill, evacuate the area immediately, ventilate thoroughly, and contain the spill with absorbent materials (e.g., sand, vermiculite)—do not flush with water directly (may spread the flammable liquid). If a fire occurs, use dry chemical extinguishers or carbon dioxide extinguishers (avoid water jets, which can disperse vapors).