Disodium 4,4'-bis(2-sulfostyryl)biphenyl

Basic information

  • Product Name:Disodium 4,4'-bis(2-sulfostyryl)biphenyl
  • CasNo.:27344-41-8
  • MF:C28H20Na2O6S2
  • MW:

Physical and Chemical Properties

  • Purity:90%
  • Boiling Point:
  • Packing:Granule
  • Throughput:
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Product Details

CasNo: 27344-41-8

MF: C28H20Na2O6S2

Appearance: Granule

Delivery Time: 15 days

Packing: 25kg/bag

Purity: 90%

1. Basic Information

  • English Name: Disodium 4,4'-bis(2-sulfostyryl)biphenyl; Fluorescent Brightener CBS-X
  • Chinese Name: 4,4'- 双 (2 - 磺酸苯乙烯基) 联苯基二钠;荧光增白剂 CBS-X;荧光增白剂 351
  • CAS Number: 27344-41-8
  • Molecular Formula: C₂₈H₂₀Na₂O₆S₂
  • Molecular Weight: 562.56 g/mol
  • Common Synonyms: Fluorescent Brightener 351; CBS-X; Disodium 4,4'-bis[(E)-2-(2-sulfophenyl)ethenyl]biphenyl
  • Appearance: Bright yellow-green granules or powder (high-quality products feature uniform particle size, no visible impurities, and consistent hue)

2. Physical and Chemical Properties

Indicator

Typical Values

Description

Melting Point/Decomposition Temperature

>300°C (decomposes without melting)

Excellent thermal stability; no degradation during standard processing (e.g., detergent spray drying at 120–150°C or textile dyeing at <100°C).

Density (25°C)

1.414 g/cm³

Consistent with granular/powdered product 形态,facilitating uniform mixing in formulations.

Solubility

- Slightly soluble in water: 17.6 g/L (20°C), 25 g/L (25°C), 100 g/L (70°C), 300 g/L (95°C)
- Slightly soluble in methanol; poorly soluble in dimethyl sulfoxide (DMSO) and non-polar solvents (e.g., ethanol, acetone)

Solubility increases with temperature; can be prepared into stable suspensions with warm water (50–70°C) for easy dosing in low-temperature formulations.

UV-Visible Absorption

Maximum absorption wavelength (λmax): 348–350 nm

Absorbs ultraviolet light in the 300–400 nm range and emits blue-green fluorescence, effectively compensating for yellow tones in substrates.

Fluorescence Emission

Maximum emission wavelength (λem): ~440 nm; Fluorescence hue: Blue-green

Enhances substrate whiteness by emitting visible light, without causing "over-blueing" (excessive cyan tones) at recommended dosages.

pH Stability

Stable at pH 6–11; slight degradation at pH <5 (acidic) or pH >12 (strongly alkaline)

Optimal usage range: pH 7–9, perfectly matching the neutral-to-weakly alkaline systems of detergents and textile dyeing baths.

Compatibility

Fully compatible with anionic surfactants (e.g., SLES, AES), non-ionic surfactants (e.g., AEO-9), and most textile auxiliaries; avoid direct mixing with cationic polymers (may cause precipitation)

No adverse reactions (e.g., sedimentation, viscosity changes) in common formulations, reducing compatibility testing efforts.

3. Key Performance Characteristics

  1. High-Efficiency Whitening and Brightening
    The stilbene-biphenyl core structure enables strong UV absorption and targeted fluorescence emission, delivering:

 

  • Whiteness Enhancement: Increases the whiteness index (ISO 105-J02) of cotton fabrics by 20%–30% and detergent powders by 15%–25% compared to untreated substrates, with long-lasting brightness retention.
  • Tone Correction: Precisely emits blue-green fluorescence to neutralize yellowish tones in textiles, paper, and detergents, resulting in a "natural white" appearance rather than an artificial blue tint.

 

  1. Excellent Durability and Process Adaptability

 

  • Wash Fastness: For cotton fabrics treated with this product, whiteness retention rate exceeds 85% after 15 washes (per ISO 105-C10), outperforming low-cost fluorescent brighteners (e.g., VBL, which retains ~70% whiteness).
  • Bleach Resistance: Maintains 90% of its brightening effect after 2-hour exposure to 0.5% sodium hypochlorite (25°C), making it suitable for chlorine-containing laundry detergents.
  • Temperature Tolerance: Stable at processing temperatures up to 150°C, compatible with high-temperature manufacturing processes such as detergent spray drying and polyester fabric dyeing.

 

  1. Environmental and Safety Advantages

 

  • Biodegradability: Meets EU ECOLABEL requirements, with a 28-day biodegradation rate of ≥60% (OECD 301B), reducing environmental accumulation compared to non-biodegradable alternatives.
  • Low Toxicity: Classified as low-toxicity; acute oral LD₅₀ (rat) >5,000 mg/kg, and skin irritation test (OECD 404) score ≤0.3 (10-point scale), safe for use in skin-contact products (e.g., soap, laundry detergents).

4. Main Application Fields

1. Detergent Industry (Core Scenario)

Product Type

Recommended Dosage

Core Function

Synthetic Laundry Detergents (powder/liquid)

0.05%–0.3%

Enhances the whiteness of washed fabrics (cotton, linen, nylon) and the visual brightness of detergent powder; compatible with enzymes and bleaching agents.

Soap/Bath Soap

0.1%–0.2%

Reduces soap yellowing during storage, improves product appearance, and imparts a subtle brightening effect to skin (no irritation).

2. Textile Industry

  • Natural Fibers (cotton, hemp): Added at 0.08%–0.2% in dyeing baths, enhances the whiteness of finished fabrics (e.g., bed sheets, clothing) without affecting fiber strength.
  • Synthetic Fibers (polyester, nylon): Suitable for one-bath whitening processes of polyester-cotton blends, providing uniform brightness across different fiber components.
  • Wool: Low-irritation formula avoids wool fiber damage, making it ideal for high-end woolen garment whitening.

3. Paper and Other Industries

  • Paper: Added at 0.03%–0.1% in papermaking pulp, brightens white paper (copy paper, tissue) and improves print clarity by reducing yellowing.
  • Plastics: Used in white plastic products (PP, PE) at 0.02%–0.05%, enhancing surface whiteness without altering plastic processing properties (e.g., melt flow rate).

5. Safety, Usage Guidelines & Storage

1. Safety Information

  • Hazard Statements (per GHS):
    • H320: Causes eye irritation.
    • H402: Harmful to aquatic life.
  • Precautionary Statements:
    • P264: Wash hands thoroughly after handling.
    • P273: Avoid release to the environment.
    • P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
    • P337+P313: If eye irritation persists: Get medical advice/attention.
    • P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

2. Usage Recommendations

  • Dosing Method: For powder formulations, mix directly with other dry ingredients (e.g., detergent builders) for uniform dispersion; for liquid formulations, dissolve in warm water (50–70°C) first to form a stable solution, then add to the system.
  • Avoid Overdosing: Excessive addition (>0.5%) may cause substrate "over-blueing" or reduced solubility, affecting product quality.

3. Packaging & Storage

  • Packaging: 25 kg/fiber drum (inner polyethylene liner) for bulk orders; 1 kg/aluminum foil bag for small-batch trials; customizable packaging available upon request.
  • Storage Conditions: Store in a cool, dry, well-ventilated warehouse (temperature 5–30°C, relative humidity <65%); avoid direct sunlight, moisture, and contact with strong acids/alkalis. Unopened products have a shelf life of 24 months.