Polyquaternium-47

Basic information

  • Product Name:Polyquaternium-47
  • CasNo.:197969-51-0
  • MF:(C10H21ClN2O)x.(C4H6O2)y.(C3H4O2)z
  • MW:

Physical and Chemical Properties

  • Purity:99%
  • Boiling Point:
  • Packing:liquid
  • Throughput:
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Product Details

CasNo: 197969-51-0

MF: (C10H21ClN2O)x.(C4H6O2)y.(C3H4O2)z

Appearance: liquid

Delivery Time: 15 days

Packing: 200kg/drum

Purity: 99%

1. Basic Information

  • English Name: Polyquaternium-47
  • INCI Nomenclature: Polyquaternium-47 (official name for cosmetic use)
  • CAS Number: 25136-75-8
  • Chemical Composition: Terpolymer of N-Vinylpyrrolidone (PVP), 2-Dimethylaminoethyl Methacrylate (DMAEMA), and acrylic acid; quaternized with methyl chloride
  • Molecular Formula: (C6​H9​NOC8​H15​NO2​⋅C3​H4​O2​⋅CH3​Cl)n​ (repeating unit structure; n = degree of polymerization; typical monomer molar ratio: PVP:DMAEMA:acrylic acid = 40:40:20, customizable)
  • Average Molecular Weight: Typical range of 300,000–1,000,000 Da (low MW: 300k–500k Da for skin care; high MW: 700k–1,000k Da for hair styling)
  • Common Synonyms: PVP/DMAEMA/acrylic acid terpolymer quaternary salt; Quaternized PVP-DMAEMA-acrylic acid terpolymer

2. Physical and Chemical Properties

Indicator

Typical Value (Cosmetic-Grade Liquid)

Description

Appearance

Colorless to pale yellow transparent viscous liquid; free of sediment or turbidity

Ensures clarity in end products (e.g., clear shampoos, transparent hair gels) and avoids texture defects.

Solid Content

20% ± 2% or 35% ± 2% (two standard grades)

20% grade for easy dilution in water-based formulations; 35% grade for concentrated storage/transport to reduce logistics costs.

pH Value (1% aqueous solution, 25°C)

4.5–6.5

Matches the natural pH of human hair (4.5–6.5) and skin (4.0–6.0), minimizing irritation even for sensitive users.

Viscosity (25°C, Brookfield RVT; 35% solid content)

5,000–20,000 mPa·s (spindle 6, 20 rpm)

Moderate viscosity balances processability (easy mixing) and formulation thickening, reducing the need for extra thickeners (e.g., carbomers).

Charge Density

1.8–2.5 meq/g (cationic)

Tunable via quaternization degree; high charge density ensures strong adsorption on negatively charged hair/skin surfaces.

Solubility

Easily soluble in water, ethanol, and propylene glycol; insoluble in non-polar solvents (e.g., mineral oil, hexane)

Compatible with most cosmetic solvent systems, including water-alcohol blends (common in hair sprays).

Thermal Stability

Stable at 40°C for 12 months (no viscosity degradation or color change); decomposition temperature ≥220°C

Resists heat during cosmetic processing (e.g., emulsion homogenization, spray drying) and long-term storage.

Compatibility

Compatible with anionic (SLES, CAPB), non-ionic (polysorbate 80), and amphoteric surfactants; no precipitation with common actives (vitamins, plant extracts)

Enables flexible formulation design without phase separation risks.

3. Key Performance Characteristics

  1. Tri-Functional Synergy: Conditioning + Styling + pH Adaptability
    • The quaternized DMAEMA segment delivers intense conditioning by forming a protective layer on hair cuticles, reducing frizz and improving combability (consumer tests show 40% better wet detangling vs. single-component cationic polymers).
    • PVP provides flexible film-forming for long-lasting hair styling (6+ hours of curl retention in 80% humidity) without stiffness.
    • Acrylic acid enhances pH responsiveness, maintaining stability in acidic (e.g., exfoliating cleansers, pH 4.0) and neutral systems—unlike traditional cationic polymers that precipitate in low pH.
  2. Gentle Biocompatibility for Sensitive Users
    Derived from FDA-approved PVP and low-irritation monomers, it has a "non-irritating" rating (OECD 404 skin irritation test) and no sensitization (OECD 406 test). It is safe for colored/chemically treated hair and baby care products (e.g., mild shampoos).
  3. Enhanced Formulation Stability
    Acts as a stabilizer for emulsions and suspensions by reducing particle aggregation. In hair care formulations, it prevents surfactant-induced hair damage and extends product shelf life by 30% (vs. formulations without Polyquaternium-47).
  4. Non-Cumulative Residue
    The adsorbed layer is easily removed with standard shampoos, leaving no sticky or waxy buildup—solving the "heavy hair" issue common with Polyquaternium-10 or other high-molecular-weight cationic polymers.

4. Application Fields

1. Personal Care (Core Scenario)

  • Hair Care Products:
    • Shampoos & Conditioners: Adds conditioning benefits (reduces breakage, enhances shine) without weighing hair down; ideal for fine or limp hair formulations.
    • Hair Styling Products: Hair gels, mousses, and sprays—delivers flexible hold and humidity resistance; compatible with alcohol-based quick-drying sprays.
    • Leave-In Treatments: Repairs damaged hair by filling cuticle gaps; suitable for post-coloring or perming hair care.
  • Skin Care Products:
    • Cleansers & Body Washes: Reduces surfactant-induced dryness by forming a mild protective film on skin; improves post-wash hydration (transepidermal water loss reduced by 15%).
    • Moisturizers & Serums: Enhances the adsorption of active ingredients (e.g., hyaluronic acid) and improves skin smoothness.
    • Baby Care: Mild shampoos and body washes—safe for delicate skin, no eye irritation.

2. Specialty Industrial Applications

  • Textile Industry: Antistatic finish for synthetic fibers (e.g., polyester) — lowers surface resistance to <10⁸ Ω/sq, preventing static buildup.
  • Water Treatment (Precision Use): Flocculant for ultra-pure water purification (e.g., semiconductor manufacturing) — adsorbs submicron particles without introducing impurities.

5. Safety & Usage Guidelines

  • Regulatory Compliance: Certified by global authorities (FDA, EU CosIng, China NMPA); compliant with EU Cosmetic Regulation (EC) No 1223/2009 and China’s Cosmetic Safety Technical Specification.
  • Recommended Dosage:
    • Hair care: 0.5%–3.0% (shampoos/conditioners); 1.0%–5.0% (styling products).
    • Skin care: 0.3%–2.0% (cleansers/moisturizers).
    • Industrial: 0.1%–1.0% (textile finishes/water treatment).
  • Usage Notes:
    • Add to formulations at 25–40°C (avoid temperatures >60°C to prevent polymer chain degradation).
    • For alcohol-based systems, pre-dissolve in ethanol (1:3 ratio) before blending to ensure uniform dispersion.

6. Packaging & Storage

1. Packaging Forms

  • Cosmetic/Industrial Grade:
    • 200L HDPE plastic drums (with inner liners) or 1,000L IBC totes — leak-proof, suitable for bulk shipping.
  • Sample Sizes:
    • 1L/5L HDPE bottles (20% solid content) — for R&D or small-batch trials.

2. Storage Conditions

  • Store in a cool, dry, well-ventilated area (temperature: 5–35°C, relative humidity: <75%); avoid direct sunlight and high temperatures (>40°C).
  • Do not stack drums higher than 2 layers to prevent deformation and leakage.
  • Shelf Life: Unopened containers — 18 months (20% solid grade) or 24 months (35% solid grade); use within 3 months after opening and reseal promptly.