TERSPERSE 4894

Basic information

  • Product Name:TERSPERSE 4894
  • CasNo.:26677-99-6
  • MF:(C4H4O4)n.(C3H4O2)n
  • MW:

Physical and Chemical Properties

  • Purity:99%
  • Boiling Point:
  • Packing:liquid
  • Throughput:
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Product Details

CasNo: 26677-99-6

MF: (C4H4O4)n.(C3H4O2)n

Appearance: liquid

Delivery Time: 15 days

Packing: 200kg/drum

Purity: 99%

1. Basic Attributes

  • Product TypePolycarboxylate-based block copolymer dispersant, with the core component being an acrylic acid-maleic anhydride block copolymer derivative. It achieves dispersion and stabilization of nanoscale particles (D50≤1μm) through synergistic steric hindrance and electrostatic repulsion effects, suitable for high-solid-content (≥70%) aqueous suspension systems. It is particularly applicable in pesticide nano-suspensions (nano-SC), high-end water-based coatings, and lithium battery electrode slurries.
  • Key Certifications: Complies with EU REACH Regulation, China’s HG/T 4575-2013 Standard for Dispersants Used in Pesticide Suspensions. It is free of nonylphenol (NP) and alkylphenol ethoxylates (APE), with a biodegradation rate of ≥85%. Some specifications meet the "low toxicity" and "low irritation" classifications in EU EC 1272/2008 CLP Regulation and can pass the US EPA pesticide adjuvant compliance certification.
  • Applicable Systems: Compatible with neutral to weakly alkaline aqueous systems (pH 6.0-10.0), highly tolerant to high electrolytes (e.g., 20% potassium sulfate solution, 15% ammonium dihydrogen phosphate solution). It can be used stably in environments with temperatures ranging from -10℃ to 55℃. It is not suitable for strongly acidic (pH < 5) or strongly reducing (e.g., containing high-concentration sodium sulfite) systems.

2. Core Physicochemical Properties

Index Item Presumed Standard Range Description
Appearance (Room Temperature) Light yellow to light brown transparent liquid No stratification or precipitation. Slight turbidity may occur at low temperatures (<5℃), and transparency is restored when heated above 10℃, without affecting performance.
Solid Content 45%-50% Represents the proportion of effective dispersing components, with a fluctuation of ≤1.5% (same batch). The content of impurities (inorganic salts, unreacted monomers) is ≤2%.
Density (25℃) 1.08-1.12 g/cm³ Stable density with an error of ≤0.015 g/cm³, facilitating precise volumetric measurement in formulations.
Weight-Average Molecular Weight 18,000-22,000 Da Moderate molecular weight balances steric hindrance and molecular chain flexibility, achieving a balance between dispersion efficiency and shear resistance.
Surface Tension (0.1% aqueous solution) 28-33 mN/m Rapidly reduces the nanoscale particle-water interfacial tension, improving wetting efficiency. The wetting time for hydrophobic nanomaterials (e.g., nano-titanium dioxide) is ≤25s.
Solubility Soluble in water, ethylene glycol, propylene glycol Excellent compatibility with nonionic surfactants (e.g., fatty alcohol polyoxyethylene ether AEO-7). It can be dispersed in some polar organic solvents (e.g., N-methylpyrrolidone).

3. Functions and Typical Application Scenarios

  • Core Functions:

    1. Nanoscale Dispersion and Long-Term Stability: Through the adsorption of carboxylic acid groups on the particle surface and the construction of a three-dimensional steric hindrance layer by polyether segments, nanoscale particles (D50≤1μm) can maintain stable suspension for 150 days without sedimentation. In pesticide nano-SC after thermal storage (54℃×14 days), the particle size growth is ≤3%, and the suspension rate remains ≥92%, far superior to traditional dispersants (particle size growth ≥8%, suspension rate ≤75%).
    2. High Solid Content and Low Viscosity Adaptation: In aqueous systems, it can increase the solid content to over 75% while controlling the system viscosity below 1000 mPa·s (25℃, 20rpm). Taking 5% abamectin nano-SC as an example, after adding this dispersant, the system viscosity decreases from 1800 mPa·s to 800 mPa·s, reducing solvent usage by 18% and lowering packaging and transportation costs.
    3. Enhanced Salt and Shear Resistance: In 20% high-salt solutions, the dispersion performance retention rate is ≥90%. It can withstand ultra-high-speed stirring at 5000r/min and the shear force of nanomills (sand mills), with a secondary agglomeration rate of particles after grinding ≤4%, suitable for industrial continuous production processes of nanomaterials and improving production efficiency.
    4. Synergistic Dispersion: When compounded with nonionic surfactants, it can produce a "synergistic dispersion effect", increasing dispersion efficiency by 15%-20%, reducing the dosage of a single dispersant, and improving the low-temperature stability of the formulation (no delamination after storage at -8℃ for 7 days).
  • Typical Application Fields:

    • Agrochemical Industry: Used in formulations such as 5% abamectin nano-SC and 10% lambda-cyhalothrin nano-SC. The recommended dosage is 3%-6%. It can increase pesticide bioavailability by more than 30% and extend the efficacy duration by 7-10 days.
    • High-End Water-Based Coatings: As a dispersant for nanomaterials such as nano-titanium dioxide (P25) and nano-alumina, with a recommended dosage of 1%-3%. It can improve coating weather resistance by 50%, achieve a hardness of above 5H, and is suitable for high-end fields such as aerospace and automobiles.
    • Lithium Battery Materials: Used in lithium battery cathode material (e.g., lithium iron phosphate, ternary material) slurries, with a recommended dosage of 2%-5%. It can optimize electrode porosity and ion conductivity, enhancing battery cycle life (1000-cycle capacity retention rate ≥85%).
    • Nanomaterial Processing: Used in the aqueous dispersion of nanomaterials such as nano-calcium carbonate and nano-zinc oxide, with a recommended dosage of 0.8%-2.5%. It can achieve a dispersed particle size D50≤100nm, meeting the application requirements of high-end functional materials (e.g., nano-coatings, nano-catalysts).

4. Usage Specifications and Precautions

  • Recommended Dosage: 3%-6% in the agrochemical field, 1%-3% in the high-end coatings field, 2%-5% in the lithium battery slurry field, and 0.8%-2.5% in the nanomaterial processing field. It is recommended to determine the optimal ratio through small-scale tests (sedimentation volume ratio test, particle size distribution test, viscosity test). Excessive addition (exceeding the recommended upper limit by 20%) may lead to increased foam in the system, which can be adjusted by adding an organic silicon defoamer (e.g., BYK-028), with the defoamer dosage being 5%-8% of the dispersant dosage.
  • Compatibility: Can be compounded with nonionic surfactants (e.g., AEO-7, NP-9) and anionic surfactants (e.g., sodium dodecylbenzene sulfonate). It is strictly prohibited to mix with high-concentration cationic surfactants (e.g., cetyltrimethylammonium bromide, dodecyldimethylbenzylammonium chloride), otherwise, ion association reaction will occur, resulting in precipitation and dispersion failure.
  • Storage Requirements: Seal and store in a cool, ventilated place (5-30℃), avoiding direct sunlight and freezing (below -10℃ may cause the active ingredient to precipitate). The unopened shelf life is 24 months, and it should be used within 6 months after opening. The remaining product should be tightly capped to prevent moisture. If irreversible delamination occurs in the solution (not restored after heating), it should not be used.
  • Safety: The acute oral toxicity LD50 (rat) >5000mg/kg, classified as practically non-toxic. Skin irritation test (rabbit) shows no irritation, and eye irritation test shows no irritation. It is recommended to wear acid and alkali-resistant gloves during operation. If it comes into contact with the skin accidentally, rinse with water, no special treatment is required. It is prohibited to store with food and feed.